Clumped isotope effects during OH and Cl oxidation of methane
نویسندگان
چکیده
منابع مشابه
Statistical clumped isotope signatures
High precision measurements of molecules containing more than one heavy isotope may provide novel constraints on element cycles in nature. These so-called clumped isotope signatures are reported relative to the random (stochastic) distribution of heavy isotopes over all available isotopocules of a molecule, which is the conventional reference. When multiple indistinguishable atoms of the same e...
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The kinetic isotope effects in the reactions of CH3Cl, CH3Cl and CD3Cl with OH radicals and Cl atoms were studied in relative rate experiments at 298±2 K and 1013±10 mbar. The reactions were carried out in a smog chamber using long path FTIR detection and the spectroscopic data analyzed employing a non-linear least squares spectral fitting method using measured highresolution infrared spectra a...
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Methane cold seep systems typically exhibit extensive buildups of authigenic carbonate minerals, resulting from local increases in alkalinity driven by methane oxidation. Here, we demonstrate that modern seep authigenic carbonates exhibit anomalously low clumped isotope values (Δ47), as much as ∼0.2‰ lower than expected values. In modern seeps, this range of disequilibrium translates into appar...
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Methane is the second most important long-lived greenhouse gas and plays a central role in the chemistry of the Earth’s atmosphere. Nonetheless there are significant uncertainties in its source budget. Analysis of the isotopic composition of atmospheric methane, including the doubly substituted species CH3D, offers new insight into the methane budget as the sources and sinks have distinct isoto...
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Rate coefficients have beenmeasured at 298 K and atmospheric pressure for the reaction of OH radicals and Cl atoms with propylene carbonate. The measurements were performed in a large volume photoreactor using in situ FTIR spectroscopy for the analysis. The following rate coefficients (in units of cm per molecule per s) were obtained: k(OH + PC) 1⁄4 (2.52 0.51) 10 12 and k(Cl + PC) 1⁄4 (1.77 0....
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ژورنال
عنوان ژورنال: Geochimica et Cosmochimica Acta
سال: 2017
ISSN: 0016-7037
DOI: 10.1016/j.gca.2016.09.012